I would agree with Duncan on this one. I was just reading New Brewing Lager Beer by Noonan, and he writes the following on the subject:
"All naturally occurring waters are dilute solutions of minerals in which small quantities of gases and organic matter may be dissolved. Rainwater should be the purest natural source of water, but because it assimilates atmospheric gases and organic mineral particles wherever the air is the least bit polluted, most rainwater is absolutely unsuitable for use in brewing. Precipitation in areas far removed from large fossil-fuel burning plants more often than not is still polluted by highly corrosive sulfuric acid. Free hydrogen carbonates...are also common in rainwater. They rob the calcium from the mash, wort, and ferment by forming bicarbonate salts that are precipitated from solution during boiling."
Based on that, I would just avoid the issue altogether by using regular water that you treat to remove the usual suspects - chlorine, chloramine, etc. If you do get adventurous and throw caution to the wind, let us know how it turns out! Good luck!